I don't know a lot of them but here are a few I'm trying to get plus some that I took note of for being different than normal.
Tamamo (Caster) and Nero Bride- 15% Arts boost to the whole party. Since Tamamo's the main Art-type support, it works well for helping build NP while also increasing damage. For Bride, it gives her a passive perma-buff that she otherwise can't give by herself.
Altria Saber Alter - NP Strength +30% and 30% chance to give a 5% Def Debuff with each normal attack. (Pretty much like the challenge quest)
VladIII (Berserker) and Kintoki (Berserker) - NP Strength +30% and 30% chance to get 5% NP charge per normal attack (RNG reliant but may be a good way to charge his NP faster.)
EMIYA - NP Strength +30% and 30% chance to get 5 crit stars per normal attack
Arash - Remove all Debuffs and restore HP of all allies by 5,000 when defeated (Given his suicidal NP, it's worth noting but since he is usually used to farm... it depends I guess)
Gilgamesh - NP Strength +30% and 30% chance to get 10% crit damage buff per normal attack (Useful due to his buster crit style)
Cu Alter - NP Strength +30% and one-time Guts (20% health)
Georgios - When defeated in battle, apply Invincible (1 time) & Damage Cut 1000 (3 turns) to all allies (As one of the hardier tanks, this adds to his usefulness if he did get killed)
Jack - Increase Critical Strength of all allies by 25% while she's on the field (With all the crit stars she generates, her Bond CE synergizes well to make use of them)
Martha (Rider), Medea Lily, and Irisviel - Increase HP Recovery received by all allies by 30%
Here's the site page if you wanna look up more.
https://fategrandorder.fandom.com/wiki/Craft_Essence_List/Max_Bond
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